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Iron-Catalyzed Coupling of Aryl Grignard Reagents with Alkyl Halides: A Competitive Hammett Study

✍ Scribed by Anna Hedström; Ulla Bollmann; Jenny Bravidor; Prof. Per-Ola Norrby

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
280 KB
Volume
17
Category
Article
ISSN
0947-6539

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## Abstract The title reaction has been studied under low temperature conditions. Coupling with active substrates can be done even at dry ice temperature. Initial rate studies at −25 °C indicate that high concentrations of any reagent can lead to either complete or partial catalyst deactivation. Un