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Iron Carbonyl Complexes of Triphenylphosphine, Triphenylarsine, and Triphenylstibine

โœ Scribed by Clifford, A. F.; Mukherjee, A. K.


Book ID
126159219
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
404 KB
Volume
2
Category
Article
ISSN
0020-1669

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The kinetics of oxidation of triphenyl derivatives of group V elements Ph3M (M = P, As Sb) by potassium peroxodisulfate have been investigated spectrophotometrically in 60% acetonitrile-40% water (v/v) mixture. The reaction follows second-order kinetics, first order in each reactant. Changes in the