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Iridoids: The Total Synthesis of the Aglucones of (±)-8-Epiloganin and (±)-Mussaenoside Via Bicyclo |3.3.0| Octenes

✍ Scribed by P. Storme; P. Callant; M. Vandewalle


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
555 KB
Volume
92
Category
Article
ISSN
0037-9646

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Total synthesis of the bicyclo[6.3.0]und
✍ Goverdhan Mehta; Jayant D Umarye 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 75 KB

The first total synthesis of the novel bicyclic sesquiterpene hydrocarbon asterisca-3(15),6-diene is reported. As a consequence, the natural product is shown to possess structure 4 with a trans-5,8 ring fusion and not the previously assigned cis-asterisca-3( 15),6-diene 3.