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Iridoid biosynthesis in staphylinid rove beetles (Coleoptera: Staphylinidae, Philonthinae)

โœ Scribed by Douglas B. Weibel; Neil J. Oldham; Birte Feld; Gereon Glombitza; Konrad Dettner; Wilhelm Boland

Book ID
117672964
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
201 KB
Volume
31
Category
Article
ISSN
0965-1748

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The unusual branched-carbon chain spiroacetal, 2,2,8-trimethyl-1,7-dioxaspiro[5.5]undecane, has been synthesised as its racemate and (6S,8R)-isomer. The natural compound, identified in the rove beetle, Ontholestes murinus (L.) proved to be the (6R,8S)-isomer. (E,E)-2,8-Dimethyi-1,7-dioxaspiro[5.5]un