Cyclometalated Complexes of Ruthenium, R
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Nicolas Pannetier; Jean-Baptiste Sortais; Jean-Thomas Issenhuth; Laurent Barloy;
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Article
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2011
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John Wiley and Sons
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English
β 266 KB
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## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridiβ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the