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Iridium(iii)-(hydrido)cyclometallated-imine complexes and metal-promoted hydrolytic cleavage of imines

✍ Scribed by P. Marcazzan; B.O. Patrick; B.R. James


Book ID
111607555
Publisher
Springer
Year
2003
Tongue
English
Weight
344 KB
Volume
52
Category
Article
ISSN
1573-9171

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## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the