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Iridium complexes with α-diimines: Catalytic hydrogen transfer from isopropanol to cyclohexanone

✍ Scribed by Mohammed Bikrani; Luz Fidalgo; María A. Garralda


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
478 KB
Volume
15
Category
Article
ISSN
0277-5387

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Catalytic hydrogen transfer activity of
✍ Mohammed Bikrani; Luz Fidalgo; María A. Garralda; Carlos Ubide 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 619 KB

## Cationic [Ir(COD)(LL)]+ species (LL = cr-diimines derived from biacetyl or glyoxal) in the presence of KOH are active catalysts in the homogeneous hydrogen transfer from isopropanol to acetophenone to give phenylethanol. The most active species is the cation containing biacetyloximehydrazone.