Catalytic hydrogen transfer activity of
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Mohammed Bikrani; Luz Fidalgo; María A. Garralda; Carlos Ubide
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Article
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1997
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Elsevier Science
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English
⚖ 619 KB
## Cationic [Ir(COD)(LL)]+ species (LL = cr-diimines derived from biacetyl or glyoxal) in the presence of KOH are active catalysts in the homogeneous hydrogen transfer from isopropanol to acetophenone to give phenylethanol. The most active species is the cation containing biacetyloximehydrazone.