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Iridium Complex-Catalyzed Allylic Amination of Allylic Esters

✍ Scribed by Takeuchi, Ryo; Ue, Naoki; Tanabe, Keisuke; Yamashita, Kengo; Shiga, Norihito

Book ID: 111653974
Publisher: American Chemical Society
Year: 2001
Tongue: English
Weight: 115 KB
Volume: 123
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja0112036

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📜 SIMILAR VOLUMES

ChemInform Abstract: Iridium Complex Cat

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Regio- and Enantioselective Allylic Amin

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Regio- and Enantioselective Allylic Amin

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Iridium Complex-Catalyzed Allylic Alkyla

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Iridium complex-catalyzed allylic alkyla

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✍ Ryo Takeuchi 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 197 KB

An iridium complex was found to be an efficient catalyst for allylic alkylation of allylic acetates with a stabilized carbon nucleophile. Two unique features of iridium complex catalysis are found. (1) Regioselective alkylation at the substituted allylic terminus: the reaction of (E)-2-alkenyl aceta