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Iridium complex bearing a chiral hydroxy-amide functionalized N-heterocyclic carbene: a catalyst precursor for asymmetric transfer hydrogenation

โœ Scribed by Hiroyuki Chiyojima; Satoshi Sakaguchi


Book ID
113930149
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
414 KB
Volume
52
Category
Article
ISSN
0040-4039

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Asymmetric transfer hydrogenation cataly
โœ Ru Jiang; Xiaoli Sun; Wei He; Hui Chen; Yongqing Kuang ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 104 KB ๐Ÿ‘ 2 views

## Abstract A novel chelated ferroceneโ€based planar chiral Nโ€heterocyclic carbeneโ€Rh(I) complex was synthesized by a simple method. It was applied to the asymmetric transfer hydrogenation of prochiral ketones. Enantioselectivities of up to 67% ee were observed. Copyright ยฉ 2009 John Wiley & Sons, L