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Iridium-Catalyzed Reactions of ω-Arylalkanols to α,ω-Diarylalkanes

✍ Scribed by Dr. Yasushi Obora; Yuka Anno; Ryuhei Okamoto; Toyomi Matsu-ura; Prof. Dr. Yasutaka Ishii

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
385 KB
Volume
123
Category
Article
ISSN
0044-8249

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✍ Kiehl, Alfried ;Eberhardt, Anke ;Müllen, Klaus 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 897 KB

## Abstract α,ω‐Dialkyl‐substituted linear polyenes are synthesized in good yields by the palladium‐catalyzed coupling reaction of trialkyltin‐ and iodo‐substituted olefinic precursors. Central building blocks are the distannylated butadiene 8 and vinyl iodide 3. Our synthetic strategy was successf