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Iridium-Catalyzed Mizoroki—Heck-Type Reaction of Organosilicon Reagents.

✍ Scribed by Tooru Koike; Xiaoli Du; Tomoyuki Sanada; Yasuaki Danda; Atsunori Mori

Publisher
John Wiley and Sons
Year
2003
Weight
172 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract Treatment of a mixture of epoxide and styrene with trimethylsilylmethylmagnesium bromide in the presence of a cobalt‐phosphine complex afforded homocinnamyl alcohol in good yield. The reaction should begin with ring opening of the epoxide by the action of magnesium bromide which leads t