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Iridium-Catalyzed H/D Exchange: Ligand Complexes with Improved Efficiency and Scope

✍ Scribed by Parmentier, Michael; Hartung, Thomas; Pfaltz, Andreas; Muri, Dieter


Book ID
127132482
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
367 KB
Volume
20
Category
Article
ISSN
0947-6539

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## Abstract Heating [Rh(dtbpy)(ΞΊ~2~‐__C,Cβ€²__‐CH~2~CMe~2~C~6~H~4~)(CH~2~CMe~2~Ph)] (1; dtbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridyl) in __p__‐xylene at 110 Β°C resulted in the formation of the 2‐__tert__‐butylphenyl complex [Rh(dtbpy)(ΞΊ~2~‐__C,Cβ€²__‐CH~2~CMe~2~C~6~H~4~)(C~6~H~4~__t__Bu‐2)] (3). Treat