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Ireland-Claisen rearrangement of substrates bearing chiral enol ether units

✍ Scribed by James P. Tellam; David R. Carbery


Book ID
113929980
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
453 KB
Volume
52
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES


Allenyl Enolates – A New Class of Chiral
✍ Becker, Markus ;Krause, Norbert 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 441 KB

## Abstract Allenic silyl ketene acetals 3 formed by conjugate 1,6‐addition of organocuprates to 2‐propen‐1‐yl and 2‐buten‐1‐yl 2‐en‐4‐ynoates 1 and regioselective enolate capture with silyl electrophiles readily undergo [3,3]‐Ireland‐Claisen rearrangements to the 2‐substituted methyl 3,4‐dienoates