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IR Study of the Interaction of Dioxygen with [meso-Triphenyl(4-pyridyl)porphyrinato]cobalt(II)

✍ Scribed by Tigran S. Kurtikyan; J. Steven Ogden; Robert K. Kazaryan; Valery N. Madakyan


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
115 KB
Volume
2003
Category
Article
ISSN
1434-1948

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The interaction of histidine, cysteine, NO and nitrite with cobalt(II) N,N',N″,N‴-tetramethyltetra-3,4-tetrapyridinoporphyrazine ([ Co ^II^ tmtppa ]^4+^) is reported. Metal-based autoreduction of [ Co ^II^ tmtppa ]^4+^ occurs with the formation of the [ Co ^I^ tmtppa (-2)]^3+^ species in the presenc