IR stimulated emission on the 2 → 1 vibrational transition of no in solid N2
✍ Scribed by J.P. Galaup; J.Y. Harbec; R. Charneau; H. Dubost
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 495 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Vibrational fluorescence of matnx-isolated NO induced by overtone pumping wti a KCI : Li colorcenier laser has been srudied in the 5 4 pm specu-al region. The IR light emitted from the directly pumped u -2 level to the u = 1 level was found lo exhibit an unusual lime dependence. Under particular conditions of geometry, pump power density and excitation frequency. intense and shon splkcs wecre observed. mdicaling Ihe oaurrenoc of stimulaled enussion. The feasibility of a solid-state \lbrational Iascr IS brief!y discussed. ' Laboratoirr w.sociC h I'Univcrsitb de F%ris-Sud. 252 VmO Ffs. L Schematk dlagrnm showhq the lowest vibratlonti lcvds of HO and the IR transltbn Involved In tho eveatone pumping eonfttralion ' 0 009-2614/85/S 03.30 0 Else&r Science Publishers B.V. (North-Holland Physics Pubiishing Division)
📜 SIMILAR VOLUMES
Based on measurements of differential scanning calorimetry, the first-order character of the spin-state transition in Fe(bt),(NCS), is established (bt = 2,2'-bi-2-thiazoline). The transition arises at T, ' =180.9 K and T,l =171.2 K, and is characterized by AH = 9.55 kO.7 kJ mol-' and AS = 54.5 \*4 J
The absolute infrared infensities of the O-I, O-2 and 1-2 vibration-rotation bands in the ' Z'gound state have been calculated from fust principles. The dipole moment function for NO+wns determined in the region of the equilibrium internuclmr separation by an accurate multi-configuration self-consis
The vibrational quenching of NO (u= I-11) by N20 in gas phase was studied by means of the time-resolved Fourier transform infrared emission spectroscopy. NO(v) was formed from the reaction of NsO and O( 'D) which was generated by laser photolysis of NsO at 193 nm. Twenty IR spectra of nx 30 ps delay