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IR Spectrum of CH 3 CN−BF 3 in Solid Neon: Matrix Effects on the Structure of a Lewis Acid−Base Complex

✍ Scribed by Eigner, Audrey A.; Rohde, John A.; Knutson, Christopher C.; Phillips, James A.


Book ID
121243713
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
770 KB
Volume
111
Category
Article
ISSN
0022-3654

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FTIR spectra of the four isotopically substituted 1:1 complexes of acetonitrile and boron trifluoride were recorded in Ar, N 2 and Xe matrices. In Ar, previously unreported three vibrational modes of the complex were clearly observed. Several significant vibrational bands were also observed in N 2 a