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IR spectroscopic study of allylperoxy radical and products of its phototransformations in the Ar matrix

✍ Scribed by E. G. Baskir; O. M. Nefedov

Book ID
112537623
Publisher
Springer
Year
1996
Tongue
English
Weight
741 KB
Volume
45
Category
Article
ISSN
1573-9171

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Under very low-pressure pyrolysis (VLPP) conditions the decomposition of 2-methyl-3,4\_diazapenta-1,3-diene proceeds via: (a) homolytic cleavage of C-N-bonds with the formation of methyl and I-methylvinyl radicals (1); (b) cleavage of double N=N-bond with the formation of N-methvi methvleneimine (3)