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Ir spectroscopic properties of hydrogen bonding in 1:1 salts of 1,8-bis(N,N-dimethylamino)naphthalene

✍ Scribed by E. Grech; Z. Malarski; L. Sobczyk


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
548 KB
Volume
129
Category
Article
ISSN
0022-2860

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📜 SIMILAR VOLUMES


The N1s ESCA Spectrum of Protonated 1,8-
✍ E. Haselbach; Anita Henriksson; F. Jachimowicz; J. Wirz 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 German ⚖ 186 KB 👁 1 views

## Abstract The ESCA spectrum of protonated 1,8‐bis‐(dimethylamino) naphthalene (“proton sponge”) (I) has been recorded in the region of N1s binding energies. The results indicate that IH^+^ possesses an __unsymmetrical__ NH…︁N hydrogen bridge.

Structure and IR spectroscopic behaviour
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X-ray diffraction and IR spectroscopic studies on the proton sponge 2,7-dichloro-1,8-bis(dimethylamino)naphthalene and its adduct with HBr were performed. It was shown that the presence of the chlorine atoms in positions 2 and 7 leads to some change of conformation with respect to the free molecule.