IR photolysis of CDF3: a study in kinetics of multiple-photon dissociation with applications to deuterium separation
✍ Scribed by Irving P. Herman; Jack B. Marling
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 543 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
CO-. laser multiple-photon dissocrntion (MPD) of CDFI is ewrnincd as a function tif tluencc and collisions, providing nea undersranding of JIPD. Notably. the dissociation yield is increased IOO-foId due ro collisions with argon. PhotochemiaIly, _ this molecule is ideally suiicd for dcuterium separation. * Work performed under the auspices of the U.S. Depxtment of Energy by the Lawrence Lib ermore Laboratory under contract number W-7405ENG-48. Length = 11 cm Absorprton frequency km -' 1 rig. 1. Lou intensity, ION resolution infmred spectrum of fluoroform nex 10 or_ Upper tracer 875 Torr CHF3 in 11 em long cell. Lower trace: 9 Torr CDF3 in 1 I cm cell.