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IR and NMR studies of parasubstituted phenyltin compounds

✍ Scribed by George Eng; Clyde R. Dillard

Book ID
104137663
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
417 KB
Volume
31
Category
Article
ISSN
0020-1693

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✦ Synopsis

Tetrakis-parasubstituted phenyltin compounds as well as the I :I addition complexes formed between tris-parasubstituted phenyltin chlorides and the Lewis bases, acetone, diethyl ether, dimethyl sulfoxide and N,N-dimethylacetamide, have been investigated by infrared and nmr spectroscopy. The results provide further evidence that in aryltin compounds dn-pn bonding exists between the empty d orbitals of the tin atom and the pi electrons of the phenyl ring, The results also indicate that substitution on the tin atom by a chlorine atom tends to enhance dn-pn bonding while substitution on the aromatic ring at the para position has little or no effect on the tin-phenyl bond.

πŸ“œ SIMILAR VOLUMES

Carbon-13 NMR parameters of phenyltin ha
Carbon-13 NMR parameters of phenyltin halogenides and phenyltin chalcogenides
✍ B. Mathiasch πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 221 KB

## Abstract The ^13^C NMR shift parameters and couplings to tin are reported for nine phenyltin halogenides and seven phenyltin chalcogenides, as well as the __T__~1~ results for Ph~2~SnTe. A pronounced linear dependence of all coupling constants on the __para__‐carbon shift is discussed.