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IR active and inactive CO adsorbed on a Pt electrode in acidic solution observed by reflection absorption spectroscopy

โœ Scribed by Yasunari Ikezawa; Hisashi Fujisawa; Futoshi Ishii

Publisher
Elsevier Science
Year
1989
Weight
50 KB
Volume
218
Category
Article
ISSN
0167-2584

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๐Ÿ“œ SIMILAR VOLUMES

CO adsorption on Pt(111) and Pt(100) sin
CO adsorption on Pt(111) and Pt(100) single crystal surfaces in aqueous solutions studied by infrared reflection-absorption spectroscopy
โœ Fusao Kitamura; Mitsuaki Takeda; Machiko Takahashi; Masatoki Ito ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 372 KB

The adsorption of CO on Pt ( I 11) and Pt ( 100) single crystal surfaces in an aqueous acid solution was studied by IRRAS and CV. On-top and bridge-bonded CO species adsorbed on Pt( I 11) and Pt( 100) electrodes were detected.

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At least two different solution species were adsorbed on a Pt(l I 1) electrode in acid solutions; one is neutral H 20, and the other the hydronium ion H3 O+. The former neutral molecule chemisorbed through an oxygen lone pair to a hydrogen covered platinum surface. At potentials more positive than 0