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IR absorption spectra of KCl and KBr crystals containing an admixture of BF4−anions

✍ Scribed by V. V. Boiko; I. Ya. Kushnirenko; Kh. K. Maksimovich

Publisher
Springer US
Year
1980
Tongue
English
Weight
613 KB
Volume
32
Category
Article
ISSN
0021-9037

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In the system BaF 2 /BF 3 /PF 5 /anhydrous hydrogen fluoride (aHF) a compound Ba(BF 4 )(PF 6 ) was isolated and characterized by Raman spectroscopy and X-ray diffraction on the single crystal. Ba(BF 4 )(PF 6 ) crystallizes in a hexagonal P62m space group with a ¼ 10.2251(4) Å, c ¼ 6.1535(4) Å, V ¼ 5

ChemInform Abstract: Syntheses, Crystal
ChemInform Abstract: Syntheses, Crystal Structures and Raman Spectra of Ba(BF4)(PF6), Ba(BF4)(AsF6) and Ba2(BF4)2(AsF6) (H3F4). The First Examples of Metal Salts Containing Simultaneously Tetrahedral BF-4 and Octahedral AF-6 Anions.
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