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Ionization thermodynamics of methylbenzoic acids in water-DMF mixtures

✍ Scribed by Jianhua Hu; Ping Zhuang; Ruisen Lin; Yongshu Xie

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
181 KB
Volume
262
Category
Article
ISSN
0040-6031

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Thermodynamic parameters of ionization of a number of substituted anilinium ions were measured in water and in ethanol-water mixtures at 25Β°C. Both the enthalpy and entropy of ionization show extreme values in a solvent mixture containing 0,90 mole fraction of water. Free energy values decrease smoo