The ionization potentials of CF4 have been determined by photoelectron spectroscopy. and comparison made xlth the values obtained by an INDO-MO calculation. The theoretical calculations are also used to identify the various ionization processes observed experimentally.
Ionization potentials of some azoalkanes by photoelectron spectroscopy
โ Scribed by Paul S. Engel; Dale B. Gerth; Dalen E. Keys; John N. Scholz; K.K. Houk; Melvin D. Rozeboom; Thomas A. Eaton; Richard S. Glass; Jeffrey L. Broeker
- Book ID
- 104203801
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 290 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4020
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โฆ Synopsis
Although photoelectron (PE) spectra have been reported for a substantial number of asoalkanes.'-" the availability of several new compounds and the possibility of correlating chemical
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mnizatlon b.md of ethyl radical bns been okcrvcd HI 3 photoelectron spectrometer. i'hc adlabdtic and ~rtic,d P's are 8.30 t: 0.02 eV and 8.55 + 0.02 cV, respcctivcly, and tbc beat ot formatIon of CzltIf is calculated to be 217.1 + "r-1 bcal/mol. Our data arc m good agreement with prcv~ou~ results.