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Ionization Potentials of Fluoroindoles and the Origin of Nonexponential Tryptophan Fluorescence Decay in Proteins ⊥

✍ Scribed by Liu, Tiqing; Callis, Patrik R.; Hesp, Ben H.; de Groot, Mattijs; Buma, Wybren Jan; Broos, Jaap


Book ID
127117563
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
173 KB
Volume
127
Category
Article
ISSN
0002-7863

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The fluorescence decay of tryptophan zwitterion in Hz0 and D20 solution was determined over the entire emission spectrum. The biexponential decay kinetics show features which are consistent with the occurrence of an excited-state reaction. This observation is not predicted by models of tryptophan ph