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Ionization potentials, electron affinities, and molecular orbitals of 2-substituted norbornadienes. Theory of 1,2 and homo-1,4 carbene cycloaddition selectivities

โœ Scribed by Houk, K. N.; Rondan, Nelson G.; Paddon-Row, Michael N.; Jefford, Charles W.; Phan Thanh Huy, ; Burrow, Paul D.; Jordan, K. D.


Book ID
118166666
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
885 KB
Volume
105
Category
Article
ISSN
0002-7863

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Cycloaddition Behavior of 2-Substituted
โœ Adam, Waldemar ;Pasquato, Lucia ;Will, Bernd ;Lucchi, Ottorino De ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 562 KB

The reaction of PTAD with 2-trimethylsilyl-, 2-chloro-, 2-cyano-, and 2-methoxycarbonylnorbornadienes 1 ad, respectively, was investigated. In all cases homo Diels-Alder adducts were obtained, for 1 a the unexpected regioisomer, the 1-trimethylsilyl derivative 2a, and for other norbornadienes 1 b-d