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Ionization potentials and electron momentum distributions for SiF4 valence-shell orbitals: an (e,2e) spectroscopic investigation and Green's function study

✍ Scribed by R. Fantoni; A. Giardini-Guidoni; R. Tiribelli; R. Cambi; M. Rosi

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 753 KB
Volume: 128
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80147-6

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✦ Synopsis

Ionization potentials and electron momentum distributions of SiF, valence-shell orbitals have been measured by means of (e,2e) spectroscopy. SCF calculations and a Green's function study have been performed on the same molecule. A comparison between experimental and theoretical results shows that a significant interaction of 2p F with 3d Si orbitals occurs.

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