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Ionization Equilibria and Conformational Transitions in Polyprotic Molecules and Polyelectrolytes

✍ Scribed by Garcés, José L.; Koper, Ger J. M.; Borkovec, Michal


Book ID
120311825
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
226 KB
Volume
110
Category
Article
ISSN
0022-3654

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Polyelectrolyte effect and conformationa
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In a polyacid consisting of polyacrylic acid attached to a polyamide matrix, marked effects in equilibrium acid-base characteristics are observed, attributable to a hindered polyelectrolyte structure. In the presence of neutral electrolyte, the very high values found for pK. drop sharply. A break in