Ionization energies of some cyclic molecules
โ Scribed by M.-Th. Praet; J. Delwiche
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 196 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The first ionization energies of cyclopentane (13.50 f 0.01 eV). cyclopentene (9.01 * 0.01 eV), me-t~yicnecyclopenbme (8.51 f 0.01 eV) and 1-methylcyclopentene (3.54 f 0.01 eV) have been measured by high-resolution photoelectron spectrometry.
Vibrational structure is found in the first electronic band of cyclopentene and 1-methylcyclopentene.
๐ SIMILAR VOLUMES
Vertical ionization energies of Liz0 (6.89 eV), L&O (3.45 eV), L&O (4.71 eV), LizS (6.51 eV), LiXS (4.11 eV), LQ (5.07 eV), Na,O (5.48 eV), Na90 (3.13 eV) and Na,O (3.60 eV) have been calculated by the Green function method using extended basis sets. The calculated IPs of the "superalkalis" L&O, Li4
The ionizaiion energies ofselenophcn. tcllurophen and a number of derivatives have been determined by the clectron impact tcchniquc. Comp;jrison of the values obtained for tellurophen with those referring to the other 5-membered rings reveals twcj major diffcrcnccs: (1) the IP of the onsubstituted