Ionization and dissociation of diethylamine by field ionization mass spectrometry
β Scribed by N. F. Zahran; A. I. Helal
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 220 KB
- Volume
- 18
- Category
- Article
- ISSN
- 1076-5174
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β¦ Synopsis
The field ionization mass spectrum of diethylamhe on a 5 pm activated wire at 300 K yields surface product ions like protonated molecular ions and doubly charged ions as well as gas phase ions like parent minus CH, group. Variations of the reaction rate as a function of the decomposition times in the range 10-11-10-6 s for the eliination of a CH, group are studied. The reaction rates are evaluated with the help of the retarding potential technique.
π SIMILAR VOLUMES
Electrospray ionization mass spectrometry (ESI-MS) has been used to determine the dissociation constants (K(D)s) and binding stoichiometry for tobramycin and paromomycin with a 27-nucleotide RNA construct representing the A-site of the 16S ribosomal RNA. K(D) values determined by holding the ligand