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Ionically conductive thin polymer films prepared by plasma polymerization—Part 8. Vapor-phase preparation of solid polymer electrolytes composed of plasma polymer and vapor-deposited lithium iodide complex

✍ Scribed by Z. Ogumi; Y. Uchimoto; E. Endo; Z. Takehara


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
218 KB
Volume
37
Category
Article
ISSN
0013-4686

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✦ Synopsis


Ultra-thin, uniform, pinhole-free solid polymer electrolyte films of approximately I,= thickness were prepared by the complexation of plasma polymerized dimethyl-2-[(2-ethoxyethoxy)ethoxy} vinylsilane (DEVS) and thermally vapor-deposited lithium iodide . The results of FT-ir and EPMA measurements indicate that the structure of the plasma polymerized DEVS is very similar to poly(DEVS) . Room temperature conductivities were as high as the order of 10 -6 S cm '(102 ohm cm2 resistance per unit area of as prepared solid polymer electrolyte).