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Ionic organoboranes. III. 1-Methyl-2-tropenyliumyl-1,2-dicarbaclovododecaborane(12) cation

✍ Scribed by Harmon, Kenneth M.; Harmon, Ann B.; Thompson, Brent C.

Book ID: 127358516
Publisher: American Chemical Society
Year: 1967
Tongue: English
Weight: 439 KB
Volume: 89
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00996a054

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The polymerization of 2-methylpropene (MP) initiated by the system di(l-azido-l-methylethyl)-1,4-benzene (DAMEB)/boron trichloride in CH,CI, solution was carried out at different temperatures and with different ratios R = [BCl,]/[DAMEB]. At low temperature and for R higher than 2, the functionalitie