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Ionic liquids in methyltrioxorhenium catalyzed epoxidation–methanolysis of glycals under homogeneous and heterogeneous conditions

✍ Scribed by Raffaele Saladino; Claudia Crestini; Marcello Crucianelli; Gianluca Soldaini; Francesca Cardona; Andrea Goti

Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
328 KB
Volume
284
Category
Article
ISSN
1381-1169

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📜 SIMILAR VOLUMES

Methyltrioxorhenium-Catalyzed Epoxidatio
Methyltrioxorhenium-Catalyzed Epoxidation-Methanolysis of Glycals under Homogeneous and Heterogeneous Conditions
✍ Andrea Goti; Francesca Cardona; Gianluca Soldaini; Claudia Crestini; Cinzia Fian 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 163 KB

## Abstract The efficient and high yielding domino epoxidation‐methanolysis of glycals **8**–**15** has been achieved by oxidation with UHP in MeOH catalyzed by MTO. The products have been conveniently isolated as 2‐acetoxy derivatives **16**–**23a, b** by direct acetylation of the crude mixtures.