Ionic liquid catalysed reaction of thiols with α,β-unsaturated carbonyl compounds—remarkable influence of the C-2 hydrogen and the anion
✍ Scribed by Sarkar, Anirban; Roy, Sudipta Raha; Chakraborti, Asit K.
- Book ID
- 115461059
- Publisher
- Royal Society of Chemistry
- Year
- 2011
- Tongue
- English
- Weight
- 674 KB
- Volume
- 47
- Category
- Article
- ISSN
- 1359-7345
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A reasonably stabilized trichloromethyl anion (TCMA) was formed by the reaction of chloroform with an electrogenerated base prepared by the electroreduction of Zpyrrolidone, and the addition of this TCIvIA to a$unsaturated esters gave the corresponding B-trichloromethyl esters in good yields.
Nucleophilic Vinylic Substitution Reactions. Part 2. Reaction of the ( Cyclopentadienyl)dicarbonyliron Anion with β-Halogeno-α,. beta.-difluorostyrenes. Influence of Ionic Association. -Reaction of Fe(CO)2(Cp)K with β-halogeno-α,β-difluorostyrenes provides the expected products of nucleophilic subst