Far-infrared spectra of alkali metal salts of sulphonated poly(ethylene terephthalate) have been measured in the 575-75 cm ~ region. For each polymeric salt, an intense and broad absorption band, the frequency of which is cation mass dependent, has been observed and assigned to cation-motion in the
Ionic interactions in sulphonated poly(ethylene terephthalate)—II. Thermal studies
✍ Scribed by Barbara Ostrowska-Gumkowska; Jadwiga Ostrowska-Czubenko
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 316 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0014-3057
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✦ Synopsis
AMtraet--The glass transition temperatures of alkali metal salts of sulphonated poly(ethylene terephthalate) were found for the range of sulphonation from 1.9 to 10.1 mol%. It was found that T. depends largely on the degree of sulphonation rather than on the detailed properties of the cation. T~ae results suggest that some change in the state of ion aggregation occurs above a sulphonation level of roughly 5 tool%, in agreement with previous findings obtained by the f.i.r, method.
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