Ionic interactions and collision dynamics in cold traps: rotational quenching of OH−(1Σ+) by Rb(2S)

Rotational-level-dependent quenching of

Rotational-level-dependent quenching of OH A 2Σ(v′ = 1) by collisions with H2O in a low-pressure flame

✍ Robert J. Cattolica; Thomas G. Mataga 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 752 KB

The collisional quenching of OH A'Z(u' = 1) by Hz0 was determined from laser-induced fluorescence measurements in the burned-gas region of stoichiometric H,/OJAr flames at low pressure ( 19 and 38 Torr). The collisional quenching was measured as a function of the initial laser-populated rotational l