Ionic Conductivity Studies in Yttrium-doped KCl Crystals
β Scribed by B. Jagan Mohan Reddy; MD. Shareefuddin; M. Narasimha Chary; Katta Narasimha Reddy
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 221 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0232-1300
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β¦ Synopsis
Ionic Conductivity Studies in Yttrium-doped KCl Crystals
Ionic conductivity measurements have been made on Potassium Chloride crystals doped with different concentrations of Yttrium, in the temperature range 200 "C to 600 "C, to understand the nature of impurity vacancy (I-V) complexes, various types of their formation and to understand how these I -V complexes affect the conduction process. The conductivity-temperature plots of KC1 : Y showed three distinct regions. These regions are explained on the basis of DRYFUS and NOWICK notation, formation and dissociation of yttrium impurity precipitates.
π SIMILAR VOLUMES
The measurements of colourability and density changes in KCI crystals with different Sr2+ contents point to the presence of two separate doping ranges in which different mechanisms of Sr2+ incorporation aro active. Below 350 ppm Sr/KC1 substitutional incorporation and above 350 ppm Sr/KCI precipitat