𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Ionic and Organometallic Reductions with N-Heterocyclic Carbene Boranes

✍ Scribed by Qianli Chu; Malika Makhlouf Brahmi; Andrey Solovyev; Shau-Hua Ueng; Dennis P. Curran; Max Malacria; Louis Fensterbank; Emmanuel Lacôte

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
200 KB
Volume
15
Category
Article
ISSN
0947-6539

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Organometallic chemistry of silver and c
Organometallic chemistry of silver and copper N-heterocyclic carbene complexes
✍ Polly L. Arnold 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 164 KB

## Abstract The only stable organometallic carbene complexes of silver and copper are those of N‐heterocyclic carbenes, since formally these robust divalent carbon ligands bind only by a σ donor interaction to the metal. A survey of the range of complexes that have now been reported is presented. ©

Linking Borane with N-Heterocyclic Carbe
Linking Borane with N-Heterocyclic Carbenes: Effective Hydrogen-Atom Donors for Radical Reactions
✍ John C. Walton 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 248 KB 👁 1 views

## Abstract **Undue influence**: N‐heterocyclic carbenes (NHCs) were found to reduce the strength of the BH bonds of borane by a surprisingly large amount upon the formation of NHC–BH~3~ complexes. This property was exploited in the development of a suite of NHC–borane complexes for the reduction

Hybrid Ligands with N-Heterocyclic Carbe
Hybrid Ligands with N-Heterocyclic Carbene and Chiral Phosphaferrocene Components
✍ Holger Willms; Walter Frank; Christian Ganter 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 435 KB

## Abstract N‐Heterocyclic carbenes (NHCs) possessing one or two 3,4‐dimethylphosphaferrocenyl substituents and either methylene or ethylene alkyl bridges have been prepared. These carbenes turned out to be remarkably stable and were characterized by NMR methods and partly by mass spectrometry. The