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Ion-radical and redox transformations of cyclic acetals (review)

✍ Scribed by D. L. Rakhmankulov; V. V. Zorin; S. S. Zlot-skii

Book ID
112361520
Publisher
Springer US
Year
1986
Tongue
English
Weight
746 KB
Volume
22
Category
Article
ISSN
0009-3122

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πŸ“œ SIMILAR VOLUMES

Radical-chain redox rearrangement of cyc
Radical-chain redox rearrangement of cyclic benzylidene acetals to benzoate esters in the presence of thiols
✍ Brian P Roberts; Teika M Smits πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 82 KB

Cyclic benzylidene acetals derived from 1,2-and 1,3-diols undergo an efficient ring-opening redox rearrangement to give benzoate esters in the presence of a peroxide initiator and a thiol, which acts as a polarity-reversal catalyst to promote the radical-chain reaction.