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Ion pairs of benzylic cations, a theoretical study

โœ Scribed by Decoret, C.; Royer, J.; Dannenberg, J. J.

Book ID
126161719
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
442 KB
Volume
46
Category
Article
ISSN
0022-3263

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โœ Kenny B. Lipkowitz; Christopher Uhegbu; Adel M. Naylor; Robert Vance ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 807 KB

Benzylic anions were studied with the semiempirical MNDO molecular orbital method. Structural changes were analyzed as metal counterions and solvents were allowed to interact with the benzylic carbon. Generally, benzylic carbanions were found to be trigonal planar but became pyramidal or bent when m