Ion pairs formed by alkali metals. Complex of caesium with 4-nitropyridine
β Scribed by Aldo Gamba; C. Oliva; M. Simonetta
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 363 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The ESR spectra oi the 4-nitropyridine/mesium systzm in dimethoxyethane have been measured in the range of temperature between -100 and +2O"C. These spectra are drastically different from those of the ion pairs obtained with the lighter tikali metals, and an interpretition is oifered.
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Complex formation with alkali and alkaline earth metal ions of cycIic octapeptides, cyclo(Phe-Pro)c, cyclo(Leu-Pro)4, and cyclo[Lys(Z)-Pro]4 was investigated in relation to conformation. In an alcohol solution, cyclo(Phe-Pro)4 did not form complexes. However, cyclo(Leu-Pro)4 and cyclo[Lys(Z)-Pro]4 f