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Ion-pair effects in electrochemistry of aromatic compounds influence of supporting electrolyte cations on half-wave potentials of the ketone-ketyl radical anion systems

✍ Scribed by M.K. Kalinowski

Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 168 KB
Volume: 7
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(70)80247-0

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✦ Synopsis

The_ i-nfluence of supporting electrolyte cations on the polarographic reduction of benzophenone and fluorenone in dimethylformamide (DMF) was studied. The experimental

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Ion-pair effects in electrochemistry of aromatic compounds. The influence of supporting electrolyte cations on the ρπ constant of Hammett's equation

✍ M.K. Kalinowski 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 289 KB

Half-wave potentials of p-substituted nitrobenzenes and benzaldehydes in dimethylformamide depend on the ionic potential $J of the cations of the electrolyte. For a series of compounds the Hammett's reaction constant, plr, is found to be a linear function of 6. This function is derived from the know