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Ion-neutral complexes and the proton-bound dimer of acetone

✍ Scribed by John A. Hunter; Chris. A. F. Johnson; John E. Parker; Gerry P. Smith

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
558 KB
Volume
26
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

High‐ and low‐energy collision‐induced dissociation, and multi‐photon infrared dissociation spectra of the proton‐bound dimer of acetone all show the formation of protonated‐acetone and an acetone molecule as the only dissociation products. In the present paper evidence is presented that the proton‐bound dimer of acetone can exist as three isomeric ion‐neutral complexes, two of which may interconvert. The dissociation channels and energetics of these three complexes are modelled using the MINDO/3 quantum chemical method.

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