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Ion-Induced Tubular Assembly of Conjugated Schiff-Base Macrocycles

✍ Scribed by Amanda J. Gallant; Mark J. MacLachlan


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
170 KB
Volume
115
Category
Article
ISSN
0044-8249

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## Acid hydrolysis of the ester function in A-( -)589-fi2-(RR)-[Co (trien) (glyOEt)C1I2+ (( -)-1) produces optically pure A-( -)589$2-(RR)-[CO (trien) (glyOH)C1I2+ (( -)-4). Hg2+ induced removal of chloride in (-)-4 follows the rate law kobs=kHg [Hg2+] with kHg=(1.36+0.03)x 1 0 -2 ~-l s -' , 25",