In the experiments of Gavis and Gill, no appreciable change of velocity or radius along the jet was observed; in all of their experiments, however, G was always negligible with respect to unity, and so eq. ( 4) is concordant with their observations but cannot be quantitatively tested thereby. For o
Ion exchange properties of polyaniline: potentiometric measurements on membranes and coated wire electrodes
β Scribed by F.B. Diniz; K.C.S. de Freitas; W.M. de Azevedo
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 454 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
Mixtures of polyaniline
with different polymeric materials were used in order to obtain mechanically stable matrices employed to prepare membranes and coated platinum electrodes. Potentiometric measurements were carried out in aqueous solutions containing either salts or acids of several anions. These measurements indicate that the matrices are more permeable to anions than to cations. The results obtained are dependent upon the radii and charge of the anions investigated. Also, the ionic mobility inside the matrices appears to be higher for protons than for other cations.
π SIMILAR VOLUMES
AbstmceThe Fe(CN)i-'\*-charge-transfer reaction was studied with anion-exchange polymercoated electrodes. SOi-and CIO; were mainly used as the anions of the background electrolyte. The electrochemical results are correlated with the equilibrium distribution of the ions between the electrolyte and th