Ion association in 2:2 complex ion electrolytes: [Co(NH3)5NO2]SO4in water-dioxane mixtures
β Scribed by William L. Masterton; Thomas Bierly
- Publisher
- Springer US
- Year
- 1976
- Tongue
- English
- Weight
- 503 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0095-9782
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π SIMILAR VOLUMES
## Abstract Rates of solvolysis of ions [Co(3Rpy)~4~Cl~2~]^+^ with __R__ = Me and Et have been measured over a range of temperatures for a series of waterβrich water + methanol mixtures to investigate the effect of changes in solvent structure on the solvolysis of complexes presenting a largely hyd
## Abstract Rates of solvolysis of complex ions [Co(3Rpy)~4~Cl~2~]^+^ with R = __Me__ and __Et__ have been determined in mixtures of water with __t__βbutyl alcohol over a range of temperatures. Extrema found in the enthalpy Ξ__H__\* and entropy Ξ__S__\* of activation are correlated with the physica