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Iododecarboxylation Reactions of α-Oxo Ketene Dithioacetals: The New Route to α-Iodo Ketene Dithioacetals.

✍ Scribed by Yu-Long Zhao; Qun Liu; Ran Sun; Qian Zhang; Xian-Xiu Xu

Publisher
John Wiley and Sons
Year
2004
Weight
127 KB
Volume
35
Category
Article
ISSN
0931-7597

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Ketene dithioacetals III: the conjugate
Ketene dithioacetals III: the conjugate addition of ketene dithioacetal anions to cyclic α,β-unsaturated ketones
✍ Frederick E. Ziegler; Coretta Chan Tam 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 205 KB

The reilutive amounts of 1,2 to 1,4 addition products of severa ketene dithioacetal anions to cycZic a,B-unsaturated ketones have been determined. The influence of solvent and counterion is reported. Methods have been reported recently which permit the aprotic 1,4 addition of dithiane anions to a,@u