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Iodocyclization of ( Z )-1-(Butyltelluro)-1,4-diorganylbut-1-en-3-ynes. Synthesis and Reactions of 3-Iodotellurophenes

✍ Scribed by Dabdoub, Miguel J.; Dabdoub, Vânia B.; Pereira, Marco A.; Zukerman-Schpector, Julio


Book ID
127341743
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
324 KB
Volume
61
Category
Article
ISSN
0022-3263

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1Z,3Z)-Butyltelluro-4-methoxy-1,3-butadiene 2 was obtained by the hydrotelluration of (Z)-1-methoxybut-1-en-3-ynes 1. The butadienyllithium 3 obtained by the Te/Li exchange reaction in the (1Z,3Z)-1butyltelluro-4-methoxy-1,3-butadiene 2 reacted with aldehydes to form the corresponding alcohols 4a-d