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Iodo-cyclizations: Novel Strategy for the Total Syntheses of Polyrhacitide A and epi -Cryptocaryolone

✍ Scribed by Mohapatra, Debendra K.; Bhimireddy, Eswar; Krishnarao, P. Sivarama; Das, Pragna P.; Yadav, J. S.


Book ID
118167521
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
993 KB
Volume
13
Category
Article
ISSN
1523-7060

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A Unified Strategy for the Asymmetric To
✍ Dipl.-Chem. Manuel C. BrΓΆhmer; Dr. Emmanuel Bourcet; Dr. Martin Nieger; Prof.β€…Dr πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 320 KB πŸ‘ 2 views

## Abstract A unified synthetic strategy for the asymmetric syntheses of the natural products diversonol and lachnoneβ€…C was developed by using the domino vinylogous aldol–oxa‐Michael reaction as the enantioselective key step. Further transformations include dihydroxylation, lactol‐opening by a Witt