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Iodine—acetophenone charge-transfer complexes

✍ Scribed by R.M. Medina; J.A. García-Vázquez; M.J. Macazaga; J.R. Masaguer

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
451 KB
Volume
40
Category
Article
ISSN
1386-1425

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✦ Synopsis

By

using a spectrophotometric method, equilibrium constants, K, for the interaction of iodine with acetophenone (I), Cbromo-acetophenone (II), 4thloro-acetophenone (III), 4-methyl-acetophenone (IV) and 4-methoxy-acetophenone (V) have been determined at 25°C in cyclohexane. These values are discussed and interpreted by using electronic and steric effects. On the other hand, various spectral constants of the shift acceptor bands have been determined. The results are interpreted by using Mulliken's theory for charge-transfer complexes.

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