Glycogen-iodine (GI) complex formation has been studied at different concentrations of iodine and glycogen. For each glycogen concentration (0.25, 0.125, 0.0625, 0.0313 g/L), the iodine concentration was varied from 0.0317 to 1.59 g/L and the absorbance readings were taken at 453 and 560 nm (GI wave
Iodine binding capacity and iodine binding energy of glycogen
β Scribed by Douglas N. Lecker; Sangeeta Kumari; Arshad Khan
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 120 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0887-624X
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β¦ Synopsis
The iodine binding capacity (IBC) of glycogen is around 0.30% (w/w) at 3ΠC. The amount of iodine complexed comprises about 12.5% of the mass of glycogen that takes part in the glycogen-iodine (GI) complex formation. This suggests involvement of four iodine atoms for every 25 anhydroglucose units (AGU, C 6 H 10 O 5 ). Since the chromophore is due to the I 4 unit within the helix of 11 AGUs, only 44% of the AGUs (11 out of 25) are involved in the complex formation. The heat of formation of the GI complex is around 040 kJ/mol of I 2 bonded. These results suggest remarkable similarities with those of the amylopectin-iodine (API) complex.
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